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Molecular Geometry & Hybridization Quiz

Put your ccl4 hybrid orbitals and iodine trichloride molecular geometry knowledge to the test!

Difficulty: Moderate
2-5mins
Learning OutcomesCheat Sheet
Paper cutout CCl4 tetrahedral model and ICl3 T shaped molecule on teal bg with quiz test of geometry and hybridization

Ready to dive into the world of shapes and bonds? This free molecular geometry quiz is your chance to master hybridization skills while testing your knowledge of ccl4 hybrid orbitals and exploring the molecular geometry of iodine trichloride. Whether you're brushing up for finals or fueling your passion for chemistry, you'll discover how to predict electron pair arrangements, bond angles, and molecular shapes like a pro. Along the way, get instant feedback on each choice to fine-tune your understanding and watch your confidence grow. Kickstart your study session with a quick molecular structure quiz and level up with targeted hybridization practice. Don't wait - begin your journey now and unlock the secrets of VSEPR theory!

What is the hybridization of the carbon atom in CCl4?
sp
sp2
sp3
sp3d
In CCl4, carbon forms four sigma bonds and has no lone pairs, which requires four equivalent hybrid orbitals. These are sp3 hybrids oriented tetrahedrally around the carbon atom. This arrangement minimizes electron-pair repulsions. Learn more: https://en.wikipedia.org/wiki/Hybridisation_(chemistry)
What is the molecular geometry of CCl4?
Tetrahedral
Trigonal planar
Linear
Trigonal pyramidal
CCl4 has four bonding pairs around carbon and no lone pairs, giving it a tetrahedral shape according to VSEPR theory. All C–Cl bonds point to the corners of a regular tetrahedron. This geometry yields equal bond angles of 109.5°. Details: https://chem.libretexts.org/Bookshelves/General_Chemistry/Textbook_Maps/Foundations_of_General_Chemistry/08%3A_Molecular_Geometry/8.03%3A_VSEPR_Theory
What is the ideal bond angle in a perfect tetrahedral molecule?
90°
120°
109.5°
180°
In a perfect tetrahedron, bond pairs are arranged to minimize repulsion, giving bond angles of approximately 109.5°. This is characteristic of sp3 hybridization. Deviation occurs only when lone pairs or multiple bonds are present. See more: https://en.wikipedia.org/wiki/Tetrahedral_molecular_geometry
How many lone pairs of electrons are on the central iodine atom in ICl3?
0
1
2
3
Iodine has seven valence electrons and forms three bonds with chlorine, using three electrons. The remaining four electrons form two lone pairs. This results in five electron domains around iodine. More info: https://chem.libretexts.org/Bookshelves/General_Chemistry/Textbook_Maps/Foundations_of_General_Chemistry/08%3A_Molecular_Geometry/8.05%3A_Molecular_Geometry
What is the molecular geometry of ICl3?
Trigonal planar
T-shaped
See-saw
Trigonal pyramidal
ICl3 has five electron domains (three bonding pairs and two lone pairs). According to VSEPR, two lone pairs occupy equatorial positions, leaving a T-shaped geometry for the bonded atoms. The bond angles are slightly less than 90° due to lone pair repulsion. Read more: https://chem.libretexts.org/Bookshelves/General_Chemistry/Textbook_Maps/Foundations_of_General_Chemistry/08%3A_Molecular_Geometry/8.06%3A_Bent%2C_T-Shaped%2C_and_Linear_Geometries
Which hybridization corresponds to a trigonal bipyramidal electron-domain geometry?
sp3
sp2
sp3d
sp3d2
Five electron domains require five hybrid orbitals, which derive from one s, three p, and one d orbital—sp3d. These orbitals arrange into a trigonal bipyramidal shape. Equatorial positions are 120° apart; axial positions are 90° from the equatorial plane. See Bent’s rule: https://en.wikipedia.org/wiki/VSEPR_theory
Which of the following molecules has an sp2-hybridized central atom?
BF3
CH4
BeCl2
NH3
BF3 has three bonding pairs and no lone pairs around boron, making it sp2-hybridized with a trigonal planar shape. CH4 is sp3, BeCl2 is sp, and NH3 is sp3 with a lone pair. The 120° bond angles in BF3 confirm sp2 hybridization. More at: https://chem.libretexts.org/Bookshelves/General_Chemistry/Map%3A_General_Chemistry_Supplement_(McQuarrie_and_Simon)/06%3A_The_Molecular_Geometry
Which molecule exhibits trigonal bipyramidal molecular geometry?
PCl5
SF4
ICl4?
PCl3
PCl5 has five bonding pairs and no lone pairs on phosphorus, giving rise to a trigonal bipyramidal shape. SF4 and ICl4? have lone pairs that alter ideal geometry, and PCl3 is trigonal pyramidal. Equatorial and axial positions are characteristic of the trigonal bipyramid. Reference: https://en.wikipedia.org/wiki/Trigonal_bipyramidal_molecular_geometry
What is the molecular geometry and hybridization of SeCl4?
T-shaped, sp3
See-saw, sp3d
Trigonal bipyramidal, sp3d2
See-saw, sp2d
SeCl4 has five electron domains (four bonding pairs and one lone pair), giving a see-saw shape. These five domains are accommodated by sp3d hybrid orbitals. The lone pair occupies an equatorial site to minimize repulsion. Further reading: https://chem.libretexts.org/Bookshelves/General_Chemistry/Textbook_Maps/Foundations_of_General_Chemistry/08%3A_Molecular_Geometry
What is the hybridization of the phosphorus atom in the phosphate ion, PO4^3-?
sp
sp2
sp3
dsp3
In PO4^3-, phosphorus is bonded to four oxygens with no lone pairs (considering resonance averages), requiring four hybrid orbitals—sp3. The tetrahedral arrangement explains equal P–O bond lengths. Although resonance delocalizes pi character, the sigma framework is sp3. See: https://en.wikipedia.org/wiki/Phosphate
Identify the molecular shape and hybridization of XeF4.
Square planar, sp3d2
Octahedral, sp3d2
Square planar, sp3d
Tetrahedral, sp3
XeF4 has six electron domains (four bonding pairs and two lone pairs), which adopt an octahedral electron-domain geometry. Two lone pairs occupy opposite positions, leaving a square planar molecular shape. Six hybrid orbitals from one s, three p, and two d orbitals give sp3d2. Learn more: https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Book%3A_Descriptive_Inorganic_Chemistry
How many sigma and pi bonds are present in a CO2 molecule?
2 sigma and 2 pi
3 sigma and 1 pi
2 sigma and 1 pi
1 sigma and 2 pi
CO2 has two equivalent C=O double bonds. Each double bond consists of one sigma and one pi bond, so in total there are two sigma bonds and two pi bonds. The molecule is linear with sp hybridization at carbon. More detail: https://en.wikipedia.org/wiki/Carbon_dioxide
Which molecule uses d2sp3 hybridization to accommodate its bonding?
SF6
PCl5
XeF4
ClF3
SF6 has six bonding pairs and no lone pairs, requiring six hybrid orbitals for an octahedral shape. These orbitals derive from two d, one s, and three p orbitals—d2sp3. PCl5 uses sp3d; XeF4 and ClF3 both use sp3d2 but differ in electron-pair count. Reference: https://en.wikipedia.org/wiki/Sulfur_hexafluoride
What is the hybridization of the central atom in SF6?
sp3d2
dsp3
d2sp3
sp3d3
SF6 has six bonding pairs and no lone pairs, requiring six hybrid orbitals formed from two d, one s, and three p orbitals. This yields a d2sp3 hybridization, giving an octahedral shape. The inclusion of two d orbitals accommodates the hypervalent sulfur. More: https://en.wikipedia.org/wiki/Sulfur_hexafluoride
Which pair of molecules both exhibit sp3d2 hybridization at their central atoms?
SF6 and BrF5
XeF4 and SF4
PCl5 and CF4
ICl3 and PF5
SF6 has six bonding pairs and no lone pairs (octahedral), and BrF5 has five bonds plus one lone pair (square pyramidal)—both use sp3d2 hybridization. XeF4 and SF4 use different counts of bonds and lone pairs, leading to distinct hybrid sets. Detailed explanation: https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Book%3A_Descriptive_Inorganic_Chemistry
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Study Outcomes

  1. Analyze sp3 Hybridization in CCl4 -

    Determine how carbon's 2s and 2p orbitals combine to form four equivalent sp3 hybrid orbitals in tetrachloromethane.

  2. Predict ICl3 Molecular Geometry -

    Apply VSEPR theory to identify the trigonal bipyramidal electron-domain arrangement and the resulting T-shaped molecular structure of iodine trichloride.

  3. Apply VSEPR Theory to Lone Pair Effects -

    Evaluate the influence of lone pair - bond pair repulsions on bond angles and overall molecular shape in polyatomic molecules.

  4. Differentiate Sigma and Pi Bond Formation -

    Recognize the role of hybrid orbitals in sigma bond creation and understand why certain molecules lack pi bonds due to hybridization.

  5. Evaluate Molecular Polarity -

    Integrate molecular geometry and bond dipoles to predict a molecule's net dipole moment and overall polarity.

  6. Reinforce Orbital Theory Through Feedback -

    Use quiz results to identify areas for improvement and solidify your understanding of hybridization and molecular geometry concepts.

Cheat Sheet

  1. VSEPR Theory Basics -

    Understanding VSEPR is your first step in any molecular geometry quiz as it predicts shapes by minimizing repulsions between electron domains. Use the mnemonic "Lone Pairs Repel Most" to remember that nonbonding pairs occupy more space than bonding pairs. Recognizing electron domain geometry sets the stage for accurate hybridization assignments.

  2. Hybridization Fundamentals -

    Hybridization explains molecular orbital shapes by mixing atomic orbitals (e.g., sp, sp2, sp3), directly linking to molecular geometry quiz questions. For example, carbon's 1 s + 3 p orbitals combine to form four sp3 hybrids in a tetrahedral arrangement. This concept underlies many structures, so practice drawing hybrid orbitals to boost recall.

  3. CCl4 Hybrid Orbitals -

    In CCl4 hybrid orbitals, carbon uses sp3 hybridization to form four equivalent σ bonds with chlorine, yielding a perfect tetrahedral shape and 109.5° bond angles. Identifying the AX4 electron-domain formula quickly confirms sp3 hybridization in your molecular geometry quiz answers. Visualizing this structure reinforces the concept of equivalent hybrid orbitals.

  4. ICl3 Molecular Geometry -

    The molecular geometry of iodine trichloride arises from an AX3E2 electron arrangement (trigonal bipyramidal), where two equatorial lone pairs produce a T-shaped molecular geometry. In iodine trichloride molecular geometry, lone pairs compress bond angles to about 87° in the plane and 180° across the axis. Remembering "T = Three bonds" helps you recall this shape under pressure.

  5. Expanded Octet & d-Orbitals -

    Iodine in ICl3 employs an expanded octet by using empty 5d orbitals, accommodating five electron domains despite its period-3 status. When mastering hybridization concepts, note that elements in period 3 or higher often exceed the octet - a favorite molecular geometry quiz twist. This expanded capacity explains many hypervalent structures you'll encounter.

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