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Molecular Geometry Practice Quiz

Ace your quiz on molecular geometry basics

Editorial: Review CompletedCreated By: Abhinandan AngraUpdated Aug 24, 2025
Difficulty: Moderate
Grade: Grade 10
Study OutcomesCheat Sheet
Paper art representing a trivia quiz on molecular geometry for high school chemistry students.

Use this molecular geometry practice quiz to check how well you can identify shapes, bond angles, and tell electron from molecular geometry with VSEPR. Work through 20 quick questions and spot gaps so you know what to review next. You'll see common shapes, from linear and bent to trigonal planar and tetrahedral.

What is the electron-domain geometry of a molecule with three bonding domains and zero lone pairs on the central atom (AX3)?
Trigonal planar [Explanation: Three electron domains arrange trigonal planar to minimize repulsion]
Trigonal bipyramidal
Linear
Tetrahedral
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SF6 adopts which molecular geometry around sulfur?
Octahedral [Explanation: Six bonding pairs around sulfur yield an octahedral molecular geometry]
Square pyramidal
Seesaw
Trigonal bipyramidal
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In VSEPR theory, lone pairs occupy more space than bonding pairs, affecting bond angles.
True
False
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What is the ideal bond angle in a perfect tetrahedral geometry?
104.5°
90°
109.5° [Explanation: Tetrahedral ideal angle is arccos(-1/3) ≈ 109.5°]
120°
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The molecular shape of CO2 is best described as
Linear [Explanation: Two electron domains on C with no lone pairs give linear]
T-shaped
Bent
Trigonal planar
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A molecule with four electron domains and one lone pair on the central atom (AX3E) has which molecular geometry?
Square pyramidal
Trigonal pyramidal [Explanation: One lone pair on tetrahedral framework gives trigonal pyramidal]
See-saw
Square planar
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In a trigonal bipyramidal electron geometry, lone pairs prefer equatorial positions to minimize repulsions.
False
True
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Which molecule is an example of a square planar molecular geometry?
CH4
BF3
XeF4 [Explanation: XeF4 has 6 electron domains with 2 lone pairs opposite, yielding square planar]
PF5
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What is the molecular geometry of SF4?
T-shaped
Square pyramidal
Seesaw [Explanation: 5 electron domains with 1 lone pair in trigonal bipyramidal gives seesaw]
Trigonal pyramidal
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What is the molecular geometry of ClF3 around the chlorine atom?
Square planar
Trigonal planar
Seesaw
T-shaped [Explanation: 5 domains with 2 lone pairs in trigonal bipyramidal gives T-shaped]
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Which molecule is linear due to sp hybridization at the central atom?
BeCl2 [Explanation: Be has two electron domains; sp hybridization gives linear]
NH3
SO2
SF6
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Which statement about trigonal bipyramidal geometry is correct?
Axial positions have smaller 90° angles to equatorial positions and experience more repulsion [Explanation: Axial sites have three 90° interactions vs two for equatorial]
Equatorial positions are closer to the central atom
All positions are equivalent
Equatorial positions have 90° to all others
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In VSEPR, electron domains include lone pairs, single bonds, double bonds, triple bonds, and single unpaired electrons.
True
False
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Which arrangement minimizes lone pair-lone pair repulsions in trigonal bipyramidal geometry?
Place lone pairs axial
One axial, one equatorial
Place lone pairs equatorial [Explanation: Equatorial sites have fewer 90° interactions, minimizing repulsion]
Positions are equivalent
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Which description matches the geometry of BrF3 in terms of electron-domain arrangement and molecular shape?
Trigonal planar; trigonal planar
Tetrahedral; bent
Trigonal bipyramidal; T-shaped [Explanation: 5 domains total, 2 lone pairs yield T-shaped molecule]
Octahedral; square planar
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For a central atom with AX4E2, what is the molecular geometry?
Square planar [Explanation: Octahedral electron geometry with opposite lone pairs is square planar]
Square pyramidal
See-saw
Trigonal pyramidal
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For a central atom with AX6E, what is the expected molecular geometry?
Octahedral-derived with one lone pair: square pyramidal [Explanation: AX5E is square pyramidal; AX6E is not typical for second-period but for VSEPR square pyramidal corresponds to AX5E]
Pentagonal pyramidal
Distorted octahedral (no standard VSEPR shape)
Monocapped octahedral
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Which pair of molecules are isoelectronic and thus share the same electron-domain geometry around the central atom?
CO2 and O3
CN- and CO [Explanation: Both have 10 valence electrons; linear around C]
NH3 and H3O+
SO2 and NO2-
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The presence of a central atom d-orbital is required to form an expanded octet geometry in VSEPR.
True
False
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Which geometry results when there are three lone pairs in an octahedral arrangement?
Trigonal planar (of lone pairs) leaving T-shaped of atoms [Explanation: AX3E3 in octahedral yields T-shaped molecular geometry]
T-shaped
Bent
See-saw
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Study Outcomes

  1. Analyze the VSEPR theory to predict molecular shapes.
  2. Identify the arrangement of electron pairs in various molecules.
  3. Apply molecular geometry principles to determine bond angles.
  4. Explain the influence of lone pairs on molecular structure.
  5. Evaluate molecular models to solve exam-style problems.

Molecular Geometry Practice Cheat Sheet

  1. Understand VSEPR Theory - VSEPR stands for Valence Shell Electron Pair Repulsion and it's like telling electrons to social distance so they avoid awkward overlaps. By minimizing these repulsions, you can predict why methane (CH₄) holds a perfect tetrahedral shape. Gear up for 3D molecule magic!
  2. Master Lewis Structures - Lewis structures let you sketch atoms and electron dots like molecular doodles. They're your roadmap for mapping bonding and lone pairs, which is key to forecasting shapes. For example, water (H₂O) flaunts two lone pairs that bend it into a friendly "V"!
  3. Distinguish Electron-Domain vs Molecular Geometry - Electron-domain geometry counts all bonding and lone-pair regions, while molecular geometry zones in on the actual atom positions. As an example, ammonia (NH₃) flaunts a tetrahedral electron-domain shell but rocks a trigonal pyramidal shape thanks to one lone pair.
  4. Recognize Common Molecular Shapes - Familiarize yourself with geometries like linear, bent, trigonal planar, pyramidal, tetrahedral, trigonal bipyramidal, and octahedral. Spot carbon dioxide (CO₂) being linear or sulfur hexafluoride (SF₆) claiming the octahedral crown - shapes speak volumes!
  5. Feel the Lone-Pair Impact - Lone pairs hog more space than bonding pairs because they repel harder, tweaking ideal bond angles. For instance, water's H - O - H angle sags to around 104.5° instead of 109.5° thanks to two lone pairs elbowing in. Lone pairs really spice up angles!
  6. Use AXₙEₘ Notation - This nifty code labels A as the central atom, X as bonded partners, and E as lone pairs. It's like a secret language: AX₂E₂ instantly tells you a molecule is bent, such as water (H₂O). Crack the code, nail the shape!
  7. Explore Bent's Rule - Bent's rule explains how atomic s and p characters shuffle to favor less electronegative groups. In mixed substituent molecules, this dance adjusts bond angles and hybridization, making angles bend or stretch. It's the quirky twist behind real-life geometry deviations!
  8. Practice Real-World Examples - Solve molecular shape puzzles to turn theory into muscle memory - exam prep never looked so playful! Projects like identifying SF₄ as a seesaw due to one lone pair on sulfur give you hands-on fluency. Grab your molecular model kit and let's roll!
  9. Link Shape to Polarity - The 3D layout of atoms tunes a molecule's dipole moment, dictating properties like solubility and boiling point. Carbon tetrachloride (CCl₄) looks polar at the bond level but overall stays nonpolar thanks to symmetric tetrahedral perfection. Geometry rules polarity!
  10. Spot VSEPR Exceptions - Not all molecules obey simple electron-pair repulsion, especially flashy transition metal complexes where lone pairs may behave shyly. Delve into cases where factors like d‑orbital effects or coordination numbers steal the spotlight. Nerd out on the quirky outliers!
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